Fourier Transform Spectroscopy of the O2 Herzberg Bands
Identifieur interne : 003A34 ( Main/Exploration ); précédent : 003A33; suivant : 003A35Fourier Transform Spectroscopy of the O2 Herzberg Bands
Auteurs : M.-F. Mérienne [France] ; A. Jenouvrier [France] ; B. Coquart [France] ; M. Carleer [Belgique] ; S. Fally [Belgique] ; R. Colin [Belgique] ; A. C. Vandaele [Belgique] ; C. Hermans [Belgique]Source :
- Journal of Molecular Spectroscopy [ 0022-2852 ] ; 2000.
Abstract
From absorption spectra obtained at high resolution by coupling a Fourier transform spectrometer to a long-path multiple reflection cell [A. Jenouvrier, M.-F. Mérienne, B. Coquart, M. Carleer, S. Fally, A. C. Vandaele, C. Hermans, and R. Colin, J. Mol. Spectrosc. 198, 136–162 (1999)] the intensities of the O2 Herzberg bands (A3Σ+u–X3Σ−g, c1Σ−u–X3Σ−g, A′3Δu–X3Σ−g) have been studied at ambient temperature. The integrated cross section values are given for the lines of the (v′–0) bands in the A3Σ+u–X3Σ−g, c1Σ−u–X3Σ−g, and A′3Δu–X3Σ−g transitions with v′ = 0–11, v′ = 2–19, and v′ = 2–12, respectively. The band oscillator strengths have been deduced and transition moments have been calculated. The total absorption values in the region of the Herzberg bands together with the photoabsorption values determined previously above the dissociation limit can be modeled by a single curve, in agreement with the continuity relationship of the cross sections through the dissociation limit.
Url:
DOI: 10.1006/jmsp.2000.8126
Affiliations:
- Belgique, France
- Champagne-Ardenne, Grand Est, Région de Bruxelles-Capitale
- Bruxelles, Reims
- Université libre de Bruxelles
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Jenouvrier, M.-F. Mérienne, B. Coquart, M. Carleer, S. Fally, A. C. Vandaele, C. Hermans, and R. Colin, J. Mol. Spectrosc. 198, 136–162 (1999)] the intensities of the O2 Herzberg bands (A3Σ+u–X3Σ−g, c1Σ−u–X3Σ−g, A′3Δu–X3Σ−g) have been studied at ambient temperature. The integrated cross section values are given for the lines of the (v′–0) bands in the A3Σ+u–X3Σ−g, c1Σ−u–X3Σ−g, and A′3Δu–X3Σ−g transitions with v′ = 0–11, v′ = 2–19, and v′ = 2–12, respectively. The band oscillator strengths have been deduced and transition moments have been calculated. The total absorption values in the region of the Herzberg bands together with the photoabsorption values determined previously above the dissociation limit can be modeled by a single curve, in agreement with the continuity relationship of the cross sections through the dissociation limit.</div></front></TEI><affiliations><list><country><li>Belgique</li><li>France</li></country><region><li>Champagne-Ardenne</li><li>Grand Est</li><li>Région de Bruxelles-Capitale</li></region><settlement><li>Bruxelles</li><li>Reims</li></settlement><orgName><li>Université libre de Bruxelles</li></orgName></list><tree><country name="France"><region name="Grand Est"><name sortKey="Merienne, M F" sort="Merienne, M F" uniqKey="Merienne M" first="M.-F." last="Mérienne">M.-F. Mérienne</name></region><name sortKey="Coquart, B" sort="Coquart, B" uniqKey="Coquart B" first="B." last="Coquart">B. Coquart</name><name sortKey="Jenouvrier, A" sort="Jenouvrier, A" uniqKey="Jenouvrier A" first="A." last="Jenouvrier">A. Jenouvrier</name></country><country name="Belgique"><region name="Région de Bruxelles-Capitale"><name sortKey="Carleer, M" sort="Carleer, M" uniqKey="Carleer M" first="M." last="Carleer">M. Carleer</name></region><name sortKey="Colin, R" sort="Colin, R" uniqKey="Colin R" first="R." last="Colin">R. Colin</name><name sortKey="Fally, S" sort="Fally, S" uniqKey="Fally S" first="S." last="Fally">S. Fally</name><name sortKey="Hermans, C" sort="Hermans, C" uniqKey="Hermans C" first="C." last="Hermans">C. Hermans</name><name sortKey="Vandaele, A C" sort="Vandaele, A C" uniqKey="Vandaele A" first="A. C." last="Vandaele">A. C. Vandaele</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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